A couple things.
First, I love that you have a E30. I have one that I daily drove for 5 years, but has rusted out pretty good and corrosion took out my fuse/relay box and I need a vehicle wiring harness for it. It’s expensive and difficult to find one that’s uncut. I can’t let it go, it’s been sitting in my yard for almost a year. So sad, but I can at least watch videos I took of driving it to reminisce. It’s the best car I ever had. I wish I had got one back when I got into cars instead of my Jetta. If I had built and taken care of a E30 like I did my Mk2, I would have one hell of a car in my garage (the Jetta is a hell of a car, but there’s just no holding candle to a E30).
Second, getting on topic, keep in mind that automotive AC refrigerants have changed roughly every 20-29 years. That just happens to be the length of time that patents can be made to last. Draw your own conclusions on that one. The point being that performance or toxicity are not the primary reasons for change.
Third, The professional A/C service sounds expensive but it’s not. See, the system is designed to be run with a precise amount of refrigerant in it. Professional service is the only reasonable way to do it correctly. It’s one of the few instances in car repair where is not cheaper to buy the tools to do a job then pay a shop to do it. It can be done properly 2 ways. First method uses manifold gauges, a bulk R-314a tank, refrigerant scale, vacuum pump, oil separator, and a oil/dye injection tool, ($1000+ roughly) and the guy doing it needs a thorough understanding of AC system operation (be worth paying well). The other way is to use a fully automatic machine that incorporates all those tools into one automated unit that is very expensive ($3000-$6000) but able to be operated by someone with limited knowledge/skill. There’s no cheap way to do it or have it done right.
If you’ve spent the time/money to do all that work, it’s absurd that you don’t want to have it professionally serviced. I would, however that you do your own research on the ideal refrigerant and oil capacities (because you’ve done custom work and the guy doing it would have to guess how to deal with it) and specify to the shop what the system capacity is. Also keep in mind at least half, but not all of the oil is removed during professional recovery, and one should not inject the full system oil capacity when doing a normal service.
I got my E30 without a complete AC system so I don’t know anything about your situation from personal experience.