the voltage of a new battery should be 12.6V give or take a little, voltages of 13.5-14.5V are with the engine running and the alternator supplying a charge to the system. 14 volts is kind of high to be honest, if you want to test the condition of your battery the crank test is a good way to go.
the simple way is have a bud stand in front of your car, turn your high beams on, crank the engine over, if the lights dim a lot or go dark when your crank the engine over, it means that the battery is probably going dead and needs a charge and possibly replaced
if you have a voltmeter your voltage when cranking should not drop below 9.6V put a voltmeter on the battery and watch the voltage readings as a friend tries to start the car, when the car tries to start if battery voltage drops below 9.6V your battery probably needs charged or replaced.
also it is important to check all connections particularly at the battery, make sure there is no corrosion and connections are tight, also check your ground connections for tightness and corrosion, same with connections to starter.